Free delivery in Phnom Penh. Safe shopping. With Fado Publisher Springer. Publication date February 18, Language English. Product Dimensions 6. Shipping Weight Book length ISBN X. ISBN Best Sellers Rank View more. Customer care. Full name:. Retype password:. Register a shipping account. Customer's code. ID card image Upload Image. Bank card image Upload Image. This non-ideal behaviour presented by b 2 -values was reported for different electrode processes e. In the light of the discussion presented above, the deviation from the ideal behaviour presented by the Tafel slope in the high overpotential domain can be mainly attributed to modifications in the double layer properties caused by the anion adsorption.
A complementary study carried out by different authors 49,50 showed the main factor affecting the electronic transfer coefficient is associated with the effect of the ion penetration in the inner region of the double layer y i -effect , which leads to a considerable modification in location of the plane of discharging ions.
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The F EOP -values clearly reveal a dependency of the ozone production on electrolyte composition. F EOP -values obtained for pure electrolytes are in good agreement with the literature reports.
Transport, Relaxation and Kinetic Processes in Electrolyte Solutions
This behaviour, contrary to the considerable improvement gained in ozone production by introduction of fluoro-compounds into the base electrolyte e. The kinetic study revealed the influence of the electrolyte composition on the OER kinetics depends on overpotential domain. Tafel slope higher than mV indicates a reduction in the apparent effective electronic transfer coefficient in the high overpotential domain.
This non-ideal behaviour was attributed mainly to the influence of the anion adsorption on the double layer properties, which is more pronounced at higher overpotentials, where a stronger interaction between the electrode surface and the anions takes place, thus leading to a considerable change in the apparent electronic transfer coefficient.
As a result the performance of the electrolyte for this process when compared to pure acid solutions is reduced. These findings support mixtures of sulphuric and perchloric acid are not good as electrolytes for electrochemical ozone production. Da Silva and W. Da Silva, L. Acta , 48 , Amadelli, R. Nova , 26 , Foller, P. Acta , 49 , Pavlov, D. Ho, J. Chernik, A.
Catalog Record: Transport, relaxation, and kinetic processes | HathiTrust Digital Library
Trasatti, S. Kramers, H. Boukamp, B. Leitzke, O. Qian, S. Hydrogen Energy , 25 , Alves, V. Acta , 44 , Li, F. Acta , 37 , Bisquert, J.
Acta , 51 , Macdonald, J. Choquette, Y. Piela, B. Brug, G. Shervedani, R. Hitz, C. Harrington, D. Acta , 32 , Kleitz, K. Acta , 45 , Ho, C. Kokarev, G. Shub, D. Acta , 46 , Fernandes, K. Conway, B. Faraday Soc. Mulder, W. Filoche, M. Eyring, H. Glasstone, S. Erdey-Gruz, T. Darowicki, K. Dzhaparidze, Dzh. Mordvinova, N. Parsons, R. Krishtalik, L. Imai, H. All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License. Services on Demand Journal.
Experimental Electrode preparation b -PbO 2 electrodes were prepared by electrodeposition at constant current from Pb NO 3 2 acid solution onto both faces of a steel micro-sphere blasted Ti-support 10x5x0.
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Role and Significance
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Exchange Discount Summary Exchange Discount -Rs. Final Price Rs. Apply Exchange. Other Specifications. This textbook proposes the tools for a treatment of transport phenomena in electrolyte solutions which does not reduce the natural complexity of multicomponent systems.
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